A Simple Empirical Method for Determination of CuOOH/CuO Redox Couple in Electrochemical Nonenzymatic Glucose Sensing
, , , , , Dang Van Thanh, 2021, In: Journal of The Electrochemical Society, 168, p. 017506
Overview
Abstract:
In this work, we introduced a model of glucose reaction at the electrode and determined the reduction potential of CuOOH/CuO
redox couple at CuO nanowires/ITO electrode (CNIE) via an empirical study. The cyclic voltage scanning of CNIE to glucose in
different concentrations of NaOH electrolyte solution was conducted using the background subtraction (BS-CV) method. By
interpolating the glucose concentration to zero based on the curve of glucose concentration versus oxidation potential in different
pH media of NaOH, the standard electrode potential of the CuOOH/CuO redox couple was calculated to be +0.433 (V vs SHE
redox couple at CuO nanowires/ITO electrode (CNIE) via an empirical study. The cyclic voltage scanning of CNIE to glucose in
different concentrations of NaOH electrolyte solution was conducted using the background subtraction (BS-CV) method. By
interpolating the glucose concentration to zero based on the curve of glucose concentration versus oxidation potential in different
pH media of NaOH, the standard electrode potential of the CuOOH/CuO redox couple was calculated to be +0.433 (V vs SHE
| Article number | 017506 |
| Journal | Journal of The Electrochemical Society |
| Volume | 168 |
| Publication status | Published - 2021 |
| ISBN | 00134651 |