Enhancement of Leaching Copper from Printed Circuit Boards of Discarded Mobile Phones Using Ultrasound–Ozone Integrated Approach
, Que Nguyen Van, , , , , , , , Jun-2023, In: Metals, 13, 1145, p. 14
Overview
Abstract:
The recovery of metals from discarded mobile phones has been of interest due to its
environmental and economic benefits. This work presents a simple and effective approach for
leaching copper (Cu) from the printed circuit boards of discarded mobile phones by combining
ultrasound and ozone approaches. The X-ray diffraction (XRD) technique and Fourier-transform
infrared spectroscopy (FT-IR) were used to characterize the solid phases, and inductively coupled
plasma optical emission spectrometry (ICP-OES) was utilized to determine the concentration of
metals in the liquid phases. The effects of several influential parameters, including ultrasound, ozone
dose, HCl concentration, liquid/solid ratio, temperature, and reaction time on the leaching efficiency
were investigated. The results showed that the optimal conditions for Cu leaching included an ozone
dose of 700 mg/h, HCl concentration of 3.0 M, liquid/solid ratio of 8, and temperature of 333 K.
Under optimal conditions, about 99% of Cu was leached after 180 min. The shrinking core model
was used to analyze the kinetics of the Cu leaching process, and the results showed that the surface
chemical reaction governs this process. The activation energy of the leaching reaction, calculated
using Two-Point form of the Arrhenius equation, was 10.852 kJ mol-1
environmental and economic benefits. This work presents a simple and effective approach for
leaching copper (Cu) from the printed circuit boards of discarded mobile phones by combining
ultrasound and ozone approaches. The X-ray diffraction (XRD) technique and Fourier-transform
infrared spectroscopy (FT-IR) were used to characterize the solid phases, and inductively coupled
plasma optical emission spectrometry (ICP-OES) was utilized to determine the concentration of
metals in the liquid phases. The effects of several influential parameters, including ultrasound, ozone
dose, HCl concentration, liquid/solid ratio, temperature, and reaction time on the leaching efficiency
were investigated. The results showed that the optimal conditions for Cu leaching included an ozone
dose of 700 mg/h, HCl concentration of 3.0 M, liquid/solid ratio of 8, and temperature of 333 K.
Under optimal conditions, about 99% of Cu was leached after 180 min. The shrinking core model
was used to analyze the kinetics of the Cu leaching process, and the results showed that the surface
chemical reaction governs this process. The activation energy of the leaching reaction, calculated
using Two-Point form of the Arrhenius equation, was 10.852 kJ mol-1
Keyword(s): ultrasound; ozone; copper; printed circuit boards; leaching efficiency
| Article number | 14 |
| Journal | Metals |
| Volume | 13 |
| Issue number | 1145 |
| Publication status | Published - Jun-2023 |